| 0 | Batman's Villains | cover | 1 | pencils: Ross Andru; inks: Dick Giordano; letters: Gaspar Saladino | Batman [Bruce Wayne]; Riddler [Enigma]; Penguin [Oswald Cobblepot]; Joker; Catwoman [Selina Kyle]; Two-Face [Harvey Dent] |
| 1 | Best of DC -- Batman's Villains | table of contents | 1 | letters: typeset | |
| 2 | This One'll Kill You, Batman, Chapter 1: And If I Laugh... | comic story | 10 | script: Denny O'Neil; pencils: Irv Novick; inks: Dick Giordano; editing: Julius Schwartz | |
| 3 | This One'll Kill You, Batman, Chapter 2: ...'Tis That I May Not Weep! | comic story | 10 | script: Denny O'Neil; pencils: Irv Novick; inks: Dick Giordano; editing: Julius Schwartz | |
| 4 | The Origin of the Joker | comic story | 1 | pencils: Denys Cowan; inks: Dick Giordano | |
| 5 | Half an Evil | comic story | 15 | script: Denny O'Neil; pencils: Neal Adams; inks: Dick Giordano; letters: John Costanza; editing: Julie Schwartz | Batman [Bruce Wayne]; Two-Face (villain); Commissioner Gordon [James Gordon]; Arthur Reeves; Alfred Pennyworth; Billy the Tramp; Robin [Dick Grayson] (flashback); Boss Maroni (flashback) |
| 6 | The Origin of Two-Face | comic story | 1 | pencils: Denys Cowan; inks: Dick Giordano | Two-Face |
| 7 | Batman's Rogue's Gallery | illustration | 3 | pencils: Denys Cowan; inks: Dick Giordano | |
| 8 | The Malay Penguin! | comic story | 17 | script: Steve Englehart; pencils: Marshall Rogers; inks: Terry Austin; colors: Jerry Serpe; letters: Milt Snapinn; editing: Julius Schwartz | |
| 9 | The Origin of the Penguin | comic story | 1 | pencils: Denys Cowan; inks: Dick Giordano | Penguin |
| 10 | Riddler on the Move! | comic story | 18 | script: Denny O'Neil; pencils: Ernie Chua; inks: Dick Giordano; editing: Julius Schwartz | Riddler; Batman; Riddler; Blair Brambel; Alfred Pennyworth |
| 11 | The Origin of the Riddler | comic story | 1 | pencils: Denys Cowan; inks: Dick Giordano | |
| 12 | The Curious Case of the Catwoman's Coincidences! | comic story | 18 | script: Denny O'Neil; pencils: Irv Novick; inks: Dick Giordano; editing: Julius Schwartz | Catwoman; Batman; "Crusher" Baines; Rudy Stern; Alfred Pennyworth; "Gentleman" Jeremiah Jimson; James Gordon |
| 13 | The Origin of the Catwoman | comic story | 1 | pencils: Denys Cowan; inks: Dick Giordano | Catwoman |
| 14 | More Batman Thrills | promo (ad from the publisher) | 1 | letters: typeset | |
| 15 | Villainy Times Five! | foreword, introduction, preface, afterword | 1 | pencils: Ross Andru; inks: Dick Giordano; letters: Gaspar Saladino | The Joker; The Penguin; Catwoman; Two-Face; The Riddler |