| 0 | - | cover | 1 | pencils: Karl Kerschl; inks: Karl Kerschl; colors: Stephane Peru | Catman [Thomas Blake]; Deadshot; Cheshire; Rag Doll [Peter Merkel]; Knockout |
| 1 | Previously, in Villains United | recap | 1 | letters: typeset | |
| 2 | - | cover reprint (on interior page) | 1 | pencils: Karl Kerschl; inks: Karl Kerschl; colors: Stephane Peru | Catman [Thomas Blake]; Deadshot; Cheshire; Rag Doll [Peter Merkel]; Knockout |
| 3 | Part One: Exposed | comic story | 22 | script: Gail Simone; pencils: Brad Walker; inks: Jimmy Palmiotti; colors: Paul Mounts; letters: Travis Lanham | Talia al Ghul [aka Talia Head]; Calculator; Catman [Thomas Blake]; Cheshire; Deadshot; Doctor Psycho; Ibac; Knockout; Lady Vic; Mad Hatter; Pistolera; Rag Doll [Peter Merkel]; Scandal; Vicious |
| 4 | - | cover reprint (on interior page) | 1 | pencils: Karl Kerschl; inks: Karl Kerschl; colors: Stephane Peru | Catman [Thomas Blake]; Deadshot; Pistolera |
| 5 | Part Two: The First Cut Is the Deepest | comic story | 22 | script: Gail Simone; pencils: Brad Walker; inks: Jimmy Palmiotti; colors: Paul Mounts; letters: Travis Lanham | |
| 6 | - | cover reprint (on interior page) | 1 | pencils: Karl Kerschl; inks: Karl Kerschl; colors: Stephane Peru | Mad Hatter; Deadshot; Scandal; Knockout |
| 7 | Part Three: The Darkest House | comic story | 22 | script: Gail Simone; pencils: Brad Walker; inks: Jimmy Palmiotti; colors: Paul Mounts; letters: Travis Lanham | the Doom Patrol (cameo) |
| 8 | - | cover reprint (on interior page) | 1 | pencils: Karl Kerschl; inks: Karl Kerschl; colors: Stephane Peru | Doom Patrol [Robotman; Elasti-Girl; Negative Man; Beast Boy; Bumblebee] |
| 9 | Part Four: Spiders on the Wind | comic story | 22 | script: Gail Simone; pencils: Brad Walker; inks: Jimmy Palmiotti; colors: Paul Mounts; letters: Travis Lanham | Secret Six [Deadshot; Catman; Ragdoll; Knockout; Scandal Savage; Mad Hatter]; Doom Patrol [Negative Man; Vox; Robotman; Bumblebee; Elasti-Girl; Mento; Beast Boy]; Vandal Savage; Cheshire; Dr. Psycho |
| 10 | - | cover reprint (on interior page) | 1 | pencils: Karl Kerschl; inks: Karl Kerschl; colors: Stephane Peru | Dr. Psycho; Secret Six [Deadshot; Knockout; Scandal Savage; Ragdoll; Catman] |
| 11 | Part Five: Life As We Know It | comic story | 22 | script: Gail Simone; pencils: Brad Walker; inks: Jimmy Palmiotti; colors: Paul Mounts; letters: Travis Lanham | Secret Six [Scandal Savage; Deadshot; Knockout; Catman; Mad Hatter; Ragdoll]; Vandal Savage; Dr. Psycho; Cheshire |
| 12 | - | cover reprint (on interior page) | 1 | pencils: Karl Kerschl; inks: Karl Kerschl; colors: Stephane Peru | Vandal Savage; Catman; Scandal Savage |
| 13 | Part Six: Cutting the Cord | comic story | 22 | script: Gail Simone; pencils: Brad Walker; inks: Jimmy Palmiotti; colors: Paul Mounts; letters: Travis Lanham | Secret Six [Mad Hatter; Catman; Deadshot; Knockout; Ragdoll; Scandal Savage]; Cheshire; Dr. Psycho; Vandal Savage |