| 0 | - | cover | 1 | script: Stan Lee; pencils: Jack Kirby; inks: Dick Ayers; colors: Stan Goldberg; letters: Artie Simek | Avengers [Thor; Wasp; Ant-Man; Iron Man; Hulk]; Loki |
| 1 | Blank pages | blank page(s) | 2 | | |
| 2 | Avengers Masterworks Volume 1 | foreword, introduction, preface, afterword | 1 | | |
| 3 | Credits | credits, title page | 1 | pencils: Jack Kirby | Giant-Man; The Wasp; Iron Man; Thor |
| 4 | Contents | table of contents | 1 | pencils: Jack Kirby | Ant-Man; The Wasp |
| 5 | Introduction | foreword, introduction, preface, afterword | 2 | script: Stan Lee; pencils: Jack Kirby | Hulk; Ant-Man; The Wasp; Iron Man |
| 6 | Endpapers | illustration | 2 | | |
| 7 | Cover - The Avengers #1 | cover reprint (on interior page) | 1 | pencils: Jack Kirby; inks: Dick Ayers; colors: Stan Goldberg; letters: Artie Simek | Avengers [Thor; Wasp; Ant-Man; Iron Man; Hulk]; Loki |
| 8 | The Coming of the Avengers! | comic story | 22 | script: Stan Lee; pencils: Jack Kirby; inks: Dick Ayers; letters: S. Rosen | Avengers [Thor [Don Blake]; Iron Man [Tony Stark]; Ant-Man [Henry Pym]; The Wasp [Janet Van Dyne]; Hulk [Bruce Banner]] (introduction, origin); Loki; a Troll; Rick Jones; The Teen Brigade; Fantastic Four [Mr. Fantastic [Reed Richards]; Invisible Girl [Sue Storm]; The Thing [Ben Grimm]; The Human Tor |
| 9 | Cover - The Avengers #2 | cover reprint (on interior page) | 1 | script: Stan Lee; pencils: Jack Kirby; inks: Sol Brodsky; letters: Artie Simek | Giant-Man; Iron Man; Thor; The Wasp; The Space Phantom |
| 10 | The Avengers Battle the Space Phantom | comic story | 22 | script: Stan Lee; pencils: Jack Kirby; inks: Paul Reinman; letters: Art Simek | The Avengers [Hulk [Bruce Banner]; Thor [Don Blake]; Iron Man [Tony Stark]; The Wasp [Janet Van Dyne]; Ant-Man/Giant-Man [Henry Pym]]; The Space Phantom (villain, introduction); Rick Jones; The Teen Brigade |
| 11 | Cover - The Avengers #3 | cover reprint (on interior page) | 1 | script: Stan Lee; pencils: Jack Kirby; inks: Paul Reinman; colors: Stan Goldberg; letters: Artie Simek | Avengers [Iron Man, Thor, Giant-Man]; Sub-Mariner; Hulk |
| 12 | The Avengers Meet... Sub-Mariner! | comic story | 25 | script: Stan Lee; pencils: Jack Kirby; inks: P. Reinman; letters: S. Rosen | The Avengers [Thor [Don Blake]; Giant-Man [Henry Pym]; The Wasp [Janet Van Dyne]; Iron Man [Tony Stark]]; The Sub-Mariner; Hulk [Bruce Banner]; Fantastic Four [The Thing [Ben Grimm]; Mr. Fantastic [Reed Richards]; The Invisible Girl [Sue Storm]; The Human Torch [Johnny Storm]]; Spider-Man [Peter Par |
| 13 | Cover - The Avengers #4 | cover reprint (on interior page) | 1 | script: Stan Lee; pencils: Jack Kirby; inks: George Roussos; colors: Stan Goldberg; letters: Artie Simek | Avengers [Captain America [Steve Rogers]; Iron Man [Tony Stark]; Thor; Giant-Man [Hank Pym]; Wasp [Janet Van Dyne]]; Sub-Mariner [Namor] |
| 14 | Captain America Joins... The Avengers! | comic story | 23 | script: Stan Lee; pencils: Jack Kirby; inks: George Roussos; letters: Art Simek | Avengers [Captain America [Steve Rogers]; Iron Man [Tony Stark]; Thor; Giant-Man [Hank Pym]; Wasp [Janet Van Dyne]]; Rick Jones; Teen Brigade; Sub-Mariner [Namor]; Atlanteans; D'Bari alien; Bucky Barnes (cameo flashback); Hulk [Bruce Banner] (cameo flashback) |
| 15 | Cover - The Avengers #5 | cover reprint (on interior page) | 1 | script: Stan Lee; pencils: Jack Kirby; inks: Sol Brodsky, Frank Giacoia; colors: Stan Goldberg; letters: Sam Rosen | The Avengers [Iron Man; Giant Man; Thor; Captain America; The Wasp; Rick Jones]; Hulk; The Lava Men |
| 16 | The Invasion of the Lava Men! | comic story | 23 | script: Stan Lee; pencils: Jack Kirby; inks: Paul Reinman; letters: S. Rosen | Iron Man; Giant-man; Wasp; Rick Jones; Captain America; Thor; The Hulk; Bruce Banner; Betty Ross; General Ross; Lava Men |
| 17 | Special Bonus | illustration | 1 | pencils: Jack Kirby | Sub-Mariner; Giant-Man; Thor; Iron Man |
| 18 | Avengers Assemble! | promo (ad from the publisher) | 1 | pencils: Jack Kirby | |