| 0 | Big Hero 6 | cover | 1 | pencils: David Nakayama; inks: David Nakayama; colors: Emily Warren | Hiro Takachiho; Baymax; Fred; Wasabi No-Ginger; Honey Lemon; Go-Go Tomago |
| 1 | Brave New Heroes! | comic story | 22 | script: Chris Claremont; pencils: David Nakayama; inks: Terry Pallot; colors: Emily Warren; letters: Ed Dukeshire | Big Hero 6 [Hiro Takachiho; Baymax; Fred (cameo); Wasabi No-Ginger; Honey Lemon; Go-Go Tomago]; Furi Wamu (guest); Whiplash (villain); Gunsmith (villain); Brute (villain) |
| 2 | Big Hero Back-Ups! | text article | 1 | script: Jordan White | |
| 3 | Big Hero 6 Sketchbook | illustration | 7 | script: David Nakayama; pencils: David Nakayama; colors: Emily Warren | |
| 4 | Big Hero 6 | character profile | 1 | script: Anthony Flamini; pencils: Clayton Henry, Gus Vazquez | Big Hero 6 (Original Team)--Sunfire; Silver Samurai; Go-Go Tomago; Honey Lemon; Hiro Takachiho; Baymax |
| 5 | Baymax | character profile | 1 | script: Anthony Flamini; pencils: David Nakayama; inks: David Nakayama | Baymax |
| 6 | Go-Go Tomago | character profile | 1 | script: Anthony Flamini; pencils: David Nakayama; inks: David Nakayama | Go-Go Tomago |
| 7 | Hiro | character profile | 1 | script: Anthony Flamini; pencils: David Nakayama; inks: David Nakayama | Hiro Takachiho |
| 8 | Honey Lemon | character profile | 1 | script: Anthony Flamini; pencils: David Nakayama; inks: David Nakayama | Honey Lemon |
| 9 | Silver Samurai | character profile | 1 | script: Anthony Flamini, Ronald Byrd, Eric Moreels; pencils: Derec Donovan | Silver Samurai |
| 10 | Sunfire | character profile | 2 | script: Anthony Flamini; pencils: Scot Eaton, John Byrne, Alan Davis | Sunfire; Rogue |
| 11 | Next Issue | promo (ad from the publisher) | 1 | pencils: David Nakayama; inks: David Nakayama; colors: Emily Warren | Honey Lemon |