| 0 | - | cover | 1 | pencils: Gene Colan; colors: Richard Isanove | Daredevil, Gladiator, Matt Murdock, Melvin Potter |
| 1 | The Marvel Masterworks Library | promo (ad from the publisher) | 1 | pencils: Jack Kirby; colors: Dean White | |
| 2 | - | credits, title page | 1 | letters: typeset | |
| 3 | Publisher's page | credits, title page | 1 | letters: typeset | |
| 4 | Credits | credits, title page | 1 | letters: typeset | |
| 5 | - | illustration | 1 | pencils: Gene Colan; inks: Frank Giacoia; colors: Stan Goldberg | Daredevil [Matt Murdock]; The Boss; The Mob |
| 6 | Contents | table of contents | 1 | letters: typeset | |
| 7 | Introduction | foreword, introduction, preface, afterword | 1 | script: Gene Colan | |
| 8 | The Tri-Man Lives! | cover reprint (on interior page) | 1 | pencils: Gene Colan; inks: Frank Giacoia; colors: Stan Goldberg; letters: Morrie Kuramoto | Daredevil; Gladiator; Masked Marauder; Tri-Man |
| 9 | The Tri-Man Lives! | comic story | 20 | script: Stan Lee; pencils: Gene Colan; inks: Frank Giacoia, Dick Ayers; colors: Stan Goldberg; letters: Sam Rosen | Daredevil [Matt Murdock]; Judge Lewis; The Owl; Karen Page; Foggy Nelson; Gladiator; Masked Marauder; Tri-Man (introduction); The Mangler (introduction); The Dancer (introduction); The Brain (introduction); Maggia |
| 10 | DD Goes Wild! | cover reprint (on interior page) | 1 | pencils: Gene Colan; inks: Frank Giacoia; colors: Stan Goldberg; letters: Morrie Kuramoto | Daredevil; Gladiator |
| 11 | DD Goes Wild! | comic story | 20 | script: Stan Lee; pencils: Gene Colan; inks: Frank Giacoia; letters: Sam Rosen | Daredevil [Matt Murdock]; Foggy Nelson; Karen Page; Maggia; Masked Marauder; Gladiator; Tri-Man; The Dancer; The Mangler; The Brain |
| 12 | - | cover reprint (on interior page) | 1 | pencils: Gene Colan; inks: Frank Giacoia; colors: Stan Goldberg; letters: Sam Rosen | Daredevil; Ka-Zar |
| 13 | The Mystery of the Midnight Stalker! | comic story | 20 | script: Stan Lee; pencils: Gene Colan; inks: Frank Giacoia; letters: Sam Rosen | Daredevil [Matt Murdock]; Ka-Zar; Zabu; The Plunderer; Foggy Nelson; Karen Page |
| 14 | Enter: The Leap-Frog! | cover reprint (on interior page) | 1 | pencils: Gene Colan; inks: Frank Giacoia; colors: Stan Goldberg; letters: Sam Rosen | Daredevil; Leap-Frog |
| 15 | Enter: The Leap-Frog! | comic story | 20 | script: Stan Lee; pencils: Gene Colan; inks: Frank Giacoia; letters: Art Simek | Daredevil [Matt Murdock] (also as Mike Murdock); Foggy Nelson; Karen Page; Leap-Frog (introduction) |
| 16 | Stilt-Man Strikes Again! | cover reprint (on interior page) | 1 | pencils: Gene Colan; inks: Frank Giacoia; colors: Stan Goldberg; letters: Sam Rosen | Daredevil; Stilt-Man; Masked Marauder |
| 17 | Stilt-Man Strikes Again | comic story | 20 | script: Stan Lee; pencils: Gene Colan; inks: Frank Giacoia, Dick Ayers; letters: Art Simek | Daredevil [also as Mike Murdock]; Foggy Nelson; Karen Page; Stilt-Man; Masked Marauder [Frank Farnum]; Leap-Frog |
| 18 | Mike Murdock Must Die! | cover reprint (on interior page) | 1 | script: Stan Lee; pencils: Gene Colan; inks: Frank Giacoia; colors: Stan Goldberg; letters: Sam Rosen | Daredevil; Spider-Man; Masked Marauder; Stilt-Man; Karen Page; Foggy Nelson |
| 19 | Mike Murdock Must Die! | comic story | 20 | script: Stan Lee; pencils: Gene Colan; inks: Frank Giacoia; letters: Art Simek | Daredevil [Matt Murdock]; Spider-Man [Peter Parker]; Foggy Nelson; Karen Page; Stilt-Man; Masked Marauder [Frank Farnum] (death) |
| 20 | Thou Shalt Not Covet Thy Neighbor's Planet! | cover reprint (on interior page) | 1 | pencils: Gene Colan; inks: Frank Giacoia; colors: Stan Goldberg; letters: Sam Rosen | Daredevil; Aliens |
| 21 | Thou Shalt Not Covet Thy Neighbor's Planet! | comic story | 20 | script: Stan Lee; pencils: Gene Colan; inks: Dick Ayers; letters: Sam Rosen | Daredevil [also as Mike Murdock]; Karen Page; Foggy Nelson; Aliens |
| 22 | Unmasked! | cover reprint (on interior page) | 1 | pencils: Gene Colan; inks: Frank Giacoia; colors: Stan Goldberg; letters: Art Simek | Daredevil [Matt Murdock]; The Boss; The Mob |
| 23 | Unmasked! | comic story | 20 | script: Stan Lee; pencils: Gene Colan; inks: John Tartaglione; letters: Sam Rosen | Daredevil [Matt Murdock]; Karen Page; Foggy Nelson; The Boss (introduction); The Mob; Masked Marauder's gang; Stan Lee |
| 24 | - | cover reprint (on interior page) | 1 | pencils: Gene Colan; inks: John Tartaglione; colors: Stan Goldberg; letters: Sam Rosen | Daredevil; Thor; Cobra; Mr. Hyde |
| 25 | --If There Should Be a Thunder God! | comic story | 20 | script: Stan Lee; pencils: Gene Colan; inks: John Tartaglione; letters: Art Simek | Daredevil [also as Mike Murdock and Thor]; Karen Page; Foggy Nelson; Cobra; Mr. Hyde; Thor [Don Blake] |
| 26 | Blind Man's Bluff! | cover reprint (on interior page) | 1 | pencils: Gene Colan, John Romita; inks: Frank Giacoia, John Romita; colors: Stan Goldberg; letters: Sam Rosen | Daredevil; Cobra; Mr. Hyde |
| 27 | Blind Man's Bluff! | comic story | 20 | script: Stan Lee; pencils: Gene Colan; inks: John Tartaglione; letters: Art Simek | Daredevil [also as Mike Murdock]; Foggy Nelson; Karen Page; Cobra; Mr. Hyde |
| 28 | ...To Fight the Impossible Fight! | cover reprint (on interior page) | 1 | pencils: Gene Colan; inks: John Tartaglione; colors: Stan Goldberg; letters: Sam Rosen | Daredevil; Cobra; Mr. Hyde |
| 29 | ...To Fight the Impossible Fight! | comic story | 20 | script: Stan Lee; pencils: Gene Colan; inks: John Tartaglione; letters: Sam Rosen | Daredevil [Matt Murdock]; Foggy Nelson; Cobra; Mr. Hyde |
| 30 | Electro and His Emissaries of Evil! | cover reprint (on interior page) | 1 | pencils: Gene Colan; inks: Frank Giacoia; colors: Stan Goldberg; letters: Art Simek | Daredevil; Stilt-Man; Electro; Leap-Frog; Gladiator; Matador |
| 31 | Electro and the Emissaries of Evil! | comic story | 39 | script: Stan Lee; pencils: Gene Colan; inks: John Tartaglione; colors: Stan Goldberg; letters: Sam Rosen | Daredevil [Matt Murdock]; Karen Page; Foggy Nelson; Electro; Matador; Gladiator; Stilt-Man; Leap-Frog |
| 32 | Inside Daredevil! | character profile | 2 | script: Stan Lee; pencils: Gene Colan; inks: John Tartaglione; colors: Stan Goldberg; letters: Sam Rosen | Daredevil; Gladiator |
| 33 | An Explanation! | comic story | 2 | script: Stan Lee; pencils: Gene Colan; inks: John Tartaglione; colors: Stan Goldberg; letters: Art Simek | Daredevil [Matt Murdock] (also as Mike Murdock) |
| 34 | Karen Page | character profile | 1 | script: Stan Lee; pencils: Gene Colan; inks: John Tartaglione; colors: Stan Goldberg; letters: Sam Rosen | Karen Page; Matt Murdock |
| 35 | Foggy Nelson | character profile | 1 | script: Stan Lee; pencils: Gene Colan; inks: John Tartaglione; colors: Stan Goldberg; letters: Sam Rosen | Foggy Nelson; Karen Page; Matt Murdock (also as Mike Murdock) |
| 36 | - | character profile | 1 | script: Stan Lee; pencils: Gene Colan; inks: John Tartaglione; colors: Stan Goldberg; letters: Sam Rosen | Ka-Zar; Zabu |
| 37 | - | character profile | 1 | script: Stan Lee; pencils: Gene Colan; inks: John Tartaglione; colors: Stan Goldberg; letters: Sam Rosen | Daredevil |
| 38 | The Galvanizing Gladiator | character profile | 1 | script: Stan Lee; pencils: Gene Colan; inks: John Tartaglione; colors: Stan Goldberg; letters: Artie Simek | Gladiator |
| 39 | The Larcenous Leap Frog | character profile | 1 | script: Stan Lee; pencils: Gene Colan; inks: John Tartaglione; colors: Stan Goldberg; letters: Art Simek | Leap-Frog |
| 40 | The Ominous Owl | character profile | 1 | script: Stan Lee; pencils: Gene Colan; inks: John Tartaglione, John Verpoorten; colors: Stan Goldberg; letters: Art Simek | The Owl |
| 41 | The Masked Marauder | character profile | 1 | script: Stan Lee; pencils: Gene Colan; inks: John Tartaglione; colors: Stan Goldberg; letters: Art Simek | Masked Marauder |
| 42 | Blueprint for an All-Purpose Billy Club! | character profile | 1 | script: Stan Lee; pencils: Gene Colan; inks: John Tartaglione; colors: Stan Goldberg; letters: Art Simek | Daredevil |
| 43 | At the Stroke of Midnight! | comic story | 3 | script: Stan Lee; pencils: Gene Colan; inks: John Tartaglione; colors: Stan Goldberg; letters: Art Simek | Stan Lee; Gene Colan |
| 44 | - | comic story | 1 | script: Stan Lee; pencils: Gene Colan; inks: Frank Giacoia; letters: Sam Rosen | Daredevil; Foggy Nelson; Karen Page; Frank Farnum |
| 45 | - | comic story | 1 | script: Stan Lee; pencils: Gene Colan; inks: Frank Giacoia; letters: Sam Rosen | Daredevil; Foggy Nelson; Karen Page; Gladiator; Maggia |
| 46 | Mike Murdock Must Die! | cover reprint (on interior page) | 1 | script: Stan Lee; pencils: Gene Colan; inks: Frank Giacoia; letters: Sam Rosen | Daredevil; Spider-Man; Masked Marauder; Stilt-Man; Karen Page; Foggy Nelson |
| 47 | - | comic story | 1 | script: Stan Lee; pencils: Gene Colan; inks: Dick Ayers; letters: Sam Rosen | Daredevil [also as Mike Murdock] |
| 48 | - | comic story | 1 | script: Stan Lee; pencils: Gene Colan; inks: John Tartaglione; letters: Art Simek | Cobra; Mr. Hyde |
| 49 | Blueprint for an All-Purpose Billy Club! | character profile | 1 | script: Stan Lee; pencils: Gene Colan; inks: John Tartaglione; letters: Art Simek | Daredevil |
| 50 | At the Stroke of Midnight! | comic story | 1 | script: Stan Lee; pencils: Gene Colan; inks: John Tartaglione; letters: Art Simek | Stan Lee; Gene Colan |
| 51 | Biographies | text article | 1 | script: John Rhett Thomas | |
| 52 | The Marvel Masterworks | promo (ad from the publisher) | 1 | script: Cory Sedlmeier | |
| 53 | - | promo (ad from the publisher) | 1 | pencils: Jack Kirby; colors: Richard Isanove | |
| 54 | - | promo (ad from the publisher) | 1 | pencils: Gene Colan; inks: Frank Giacoia | |