| 0 | - | cover | 1 | pencils: Jack Kirby; inks: Dean White; colors: Dean White | Ant-Man, Bruce Banner, Thor Odinson, Hulk, Iron Man, Loki, Hank Pym, Tony Stark, Thor, Janet Van Dyne, Wasp |
| 1 | Title Page and Credits | credits, title page | 4 | pencils: Jack Kirby; inks: George Roussos; colors: Stan Goldberg | |
| 2 | Contents | table of contents | 1 | letters: typeset | |
| 3 | Introduction | foreword, introduction, preface, afterword | 2 | script: Stan Lee | |
| 4 | - | cover reprint (on interior page) | 1 | script: Stan Lee; pencils: Jack Kirby; inks: Dick Ayers; colors: Stan Goldberg; letters: Artie Simek, Sol Brodsky | The Avengers [Thor [Thor Odinson; Donald Blake]; Wasp [Janet Van Dyne]; Ant-Man [Henry Pym]; Iron Man [Tony Stark]; Hulk [Bruce Banner]]; Loki [Loki Laufeyson] |
| 5 | The Coming of the Avengers! | comic story | 22 | script: Stan Lee; pencils: Jack Kirby; inks: Dick Ayers; colors: Stan Goldberg; letters: Sam Rosen; editing: Stan Lee | The Avengers [Thor [Thor Odinson; Donald Blake]; Iron Man [Tony Stark]; Ant-Man [Henry Pym]; Wasp [Janet Van Dyne]; Hulk [Bruce Banner; Mechano]] (introduction, origin); circus ringmaster; lion tamer; trapeze artists; Bobby; Bobby's mother; Charlie; Captain; Jane Foster; Asgardians [Odin]; Teen Brig |
| 6 | - | cover reprint (on interior page) | 1 | script: Stan Lee; pencils: Jack Kirby; inks: Sol Brodsky; colors: Stan Goldberg; letters: Artie Simek | The Avengers [Giant-Man [Hank Pym]; Iron Man [Tony Stark]; Thor [Donald Blake]; The Wasp]; The Space Phantom |
| 7 | The Avengers Battle the Space Phantom | comic story | 22 | script: Stan Lee; pencils: Jack Kirby; inks: Paul Reinman; colors: Stan Goldberg; letters: Artie Simek; editing: Stan Lee | The Avengers [Hulk [Bruce Banner]; Thor [Don Blake]; Iron Man [Tony Stark]; The Wasp [Janet Van Dyne]; Ant-Man/Giant-Man [Henry Pym]]; The Space Phantom (villain, introduction); Rick Jones; The Teen Brigade |
| 8 | Next Issue... | promo (ad from the publisher) | 1 | script: Stan Lee; pencils: Jack Kirby; inks: Sol Brodsky; colors: Stan Goldberg; letters: Artie Simek | The Avengers [Hulk [Bruce Banner]; Giant-Man [Hank Pym]; Iron Man [Tony Stark]; Thor [Donald Blake]]; Namor the Sub-Mariner |
| 9 | The Hulk and Sub-Mariner vs. the Avengers! | cover reprint (on interior page) | 1 | script: Stan Lee; pencils: Jack Kirby; inks: Paul Reinman; colors: Stan Goldberg; letters: Artie Simek | The Avengers [Iron Man [Tony Stark]; Thor [Donald Blake]; Giant-Man [Hank Pym]]; Namor the Sub-Mariner; Hulk [Bruce Banner] |
| 10 | The Avengers Meet... Sub-Mariner! | comic story | 25 | script: Stan Lee; pencils: Jack Kirby; inks: Paul Reinman; colors: Stan Goldberg; letters: Sam Rosen; editing: Stan Lee | The Avengers [Thor [Don Blake]; Giant-Man [Henry Pym]; The Wasp [Janet Van Dyne]; Iron Man [Tony Stark]]; Namor the Sub-Mariner; Hulk [Bruce Banner]; Fantastic Four [The Thing [Ben Grimm]; Mr. Fantastic [Reed Richards]; The Invisible Girl [Sue Storm]; The Human Torch [Johnny Storm]]; Spider-Man [Pet |
| 11 | Captain America Lives Again! | cover reprint (on interior page) | 1 | script: Stan Lee; pencils: Jack Kirby; inks: George Roussos; colors: Stan Goldberg; letters: Artie Simek | The Avengers [Captain America [Steve Rogers]; Iron Man [Tony Stark]; Thor; Giant-Man [Hank Pym]; Wasp [Janet Van Dyne]]; Namor the Sub-Mariner |
| 12 | Captain America Joins... the Avengers! | comic story | 23 | script: Stan Lee; pencils: Jack Kirby; inks: George Roussos; colors: Stan Goldberg; letters: Artie Simek; editing: Stan Lee | The Avengers [Captain America [Steve Rogers]; Iron Man [Tony Stark]; Thor; Giant-Man [Hank Pym]; Wasp [Janet Van Dyne]]; Rick Jones; Teen Brigade; Namor the Sub-Mariner; Atlanteans; a D'Bari; Bucky Barnes (cameo flashback); Hulk [Bruce Banner] (cameo flashback) |
| 13 | The Invasion of the Lava Men! | cover reprint (on interior page) | 1 | script: Stan Lee; pencils: Jack Kirby; inks: Sol Brodsky, Frank Giacoia; colors: Stan Goldberg; letters: Sam Rosen | The Avengers [Captain America [Steve Rogers]; Giant-Man [Henry Pym]; Iron Man [Tony Stark]; Thor [Donald Blake]; Wasp [Janet Van Dyne]]; Rick Jones; Hulk [Bruce Banner]; Lava Men |
| 14 | The Invasion of the Lava Men! | comic story | 23 | script: Stan Lee; pencils: Jack Kirby; inks: Paul Reinman; letters: Sam Rosen; editing: Stan Lee | The Avengers [Captain America [Steve Rogers]; Giant-Man [Henry Pym]; Iron Man [Tony Stark]; Thor [Donald Blake]; Wasp [Janet Van Dyne]]; Rick Jones; Teen Brigade; Jane Foster; Betty Ross; General Thunderbolt Ross; Molto |
| 15 | Introducing Zemo! and His Masters of Evil! | cover reprint (on interior page) | 1 | script: Stan Lee; pencils: Jack Kirby; inks: Chic Stone; colors: Stan Goldberg; letters: Sam Rosen | The Avengers [Captain America [Steve Rogers]; Giant-Man [Henry Pym]; Iron Man [Tony Stark]; Thor [Donald Blake]; Wasp [Janet Van Dyne]]; Rick Jones; Masters of Evil [Baron Zemo [Heinrich Zemo]; Radioactive Man [Chen Lu]; Melter [Bruno Hogan]; Black Knight [Nathan Garrett]] |
| 16 | The Mighty Avengers Meet the Masters of Evil! | comic story | 23 | script: Stan Lee; pencils: Jack Kirby; inks: Chic Stone; colors: Stan Goldberg; letters: Sam Rosen; editing: Stan Lee | The Avengers [Captain America [Steve Rogers]; Giant-Man [Henry Pym]; Iron Man [Tony Stark]; Thor [Donald Blake]; Wasp [Janet Van Dyne]]; Rick Jones; Teen Brigade; Pate-Pot Pete [Peter Petruski]; Masters of Evil [Baron Zemo [Heinrich Zemo] (introduction); Radioactive Man [Chen Lu]; Melter [Bruno Hoga |
| 17 | Their Darkest Hour! | cover reprint (on interior page) | 1 | script: Stan Lee; pencils: Jack Kirby; inks: Chic Stone; colors: Stan Goldberg; letters: Sam Rosen | The Avengers [Captain America [Steve Rogers]; Giant-Man [Henry Pym]; Iron Man [Tony Stark]; Thor [Donald Blake]; Wasp [Janet Van Dyne]]; Rick Jones; Masters of Evil [Baron Zemo [Heinrich Zemo]; Enchantress [Amora]; Executioner [Skurge]] |
| 18 | Their Darkest Hour! | comic story | 22 | script: Stan Lee; pencils: Jack Kirby; inks: Chic Stone; colors: Stan Goldberg; letters: Artie Simek; editing: Stan Lee | The Avengers [Captain America [Steve Rogers]; Giant-Man [Henry Pym]; Iron Man [Tony Stark]; Thor [Donald Blake]; Wasp [Janet Van Dyne]]; Rick Jones; Odin; Loki; Masters of Evil [Baron Zemo [Heinrich Zemo]; Enchantress [Amora]; Executioner [Skurge]] |
| 19 | Kang, the Conqueror! | cover reprint (on interior page) | 1 | script: Stan Lee; pencils: Jack Kirby; inks: Dick Ayers; colors: Stan Goldberg; letters: Sam Rosen | The Avengers [Captain America [Steve Rogers]; Giant-Man [Henry Pym]; Iron Man [Tony Stark]; Thor [Donald Blake]; Wasp [Janet Van Dyne]]; Rick Jones; Kang |
| 20 | Kang, The Conqueror! | comic story | 21 | script: Stan Lee; pencils: Jack Kirby; inks: Dick Ayers; letters: Sam Rosen; editing: Stan Lee | The Avengers [Iron Man [Tony Stark]; Giant-Man [Hank Pym]; Captain America [Steve Rogers]; Thor [Don Blake]; Wasp [Janet Van Dyne]]; Rick Jones; Teen Brigade; Kang the Conqueror (introduction, villain) |
| 21 | Marvel Proudly Introduces... Wonder Man | cover reprint (on interior page) | 1 | script: Stan Lee; pencils: Jack Kirby; inks: Chic Stone; colors: Stan Goldberg; letters: Artie Simek | The Avengers [Captain America [Steve Rogers]; Giant-Man [Henry Pym]; Iron Man [Tony Stark]; Thor [Donald Blake]; Wasp [Janet Van Dyne]]; Wonder Man [Simon Williams]; Masters of Evil [Baron Zemo [Heinrich Zemo]; Enchantress [Amora]; Executioner [Skurge]] |
| 22 | The Coming of the... Wonder Man! | comic story | 21 | script: Stan Lee; pencils: Don Heck; inks: Dick Ayers; letters: Art Simek; editing: Stan Lee | The Avengers [Captain America [Steve Rogers]; Giant-Man [Henry Pym]; Iron Man [Tony Stark]; Thor [Donald Blake]; Wasp [Janet Van Dyne]]; Jane Foster; Teen Brigade; Wonder Man [Simon Williams] (introduction, origin); Masters of Evil [Baron Zemo [Heinrich Zemo]; Enchantress [Amora]; Executioner [Skurg |
| 23 | The Avengers Break Up! | cover reprint (on interior page) | 1 | script: Stan Lee; pencils: Jack Kirby; inks: Chic Stone; colors: Stan Goldberg; letters: Sam Rosen | The Avengers [Captain America [Steve Rogers]; Giant-Man [Henry Pym]; Iron Man [Tony Stark]; Thor [Donald Blake]; Wasp [Janet Van Dyne]]; Immortus |
| 24 | The Avengers Break Up! | comic story | 20 | script: Stan Lee; pencils: Don Heck; inks: Dick Ayers; letters: Sam Rosen; editing: Stan Lee | The Avengers [Captain America [Steve Rogers]; Giant-Man [Henry Pym]; Iron Man [Tony Stark]; Thor [Donald Blake]; Wasp [Janet Van Dyne]]; Rick Jones; Teen Brigade (cameo); Masters of Evil [Baron Zemo [Heinrich Zemo]; Enchantress [Amora]; Executioner [Skurge]]; Immortus (introduction); Paul Bunyan; At |
| 25 | The One and Only "Cap" | illustration | 1 | pencils: Jack Kirby; inks: Sol Brodsky; letters: Artie Simek | Captain America [Steve Rogers] |
| 26 | - | promo (ad from the publisher) | 1 | script: Stan Lee | |
| 27 | Don't Miss Another Big One from Marvel! | promo (ad from the publisher) | 1 | script: Stan Lee; pencils: Jack Kirby; inks: Dick Ayers; colors: Stan Goldberg; letters: Artie Simek, Sol Brodsky | |
| 28 | 72 Big Pages | promo (ad from the publisher) | 1 | script: Stan Lee; pencils: Jack Kirby; inks: Dick Ayers, Sol Brodsky; colors: Stan Goldberg; letters: Artie Simek | |
| 29 | Avengers #4 Cover Original Art | illustration | 1 | pencils: Jack Kirby; inks: George Roussos | The Avengers [Captain America [Steve Rogers]; Iron Man [Tony Stark]; Thor; Giant-Man [Hank Pym]; Wasp [Janet Van Dyne]]; Namor the Sub-Mariner |
| 30 | Biographies | text article | 2 | script: John Rhett Thomas | |